author
Bobby Brown
Perbarui 2024-10-25
PFA Material Characterization

Contents


What is PFA Material?

PFA (Perfluoroalkoxy Alkane) is a high-performance fluoropolymer in the same family as PTFE and FEP. Known for its chemical resistance, high-temperature tolerance, and excellent insulation, PFA is created by copolymerizing perfluoroalkyl vinyl ether with tetrafluoroethylene. It combines the stability of PTFE with the processability of FEP, making it ideal for chemical, semiconductor, electronics, and medical applications.

Chemical and Physical Properties of PFA

Structure and Acid-Base Resistance


The molecular structure of PFA (Perfluoroalkoxy Alkane) provides excellent stability in harsh chemical environments, resisting nearly all acids, bases, and organic solvents. This makes PFA an ideal choice for corrosion-resistant equipment in the chemical industry, such as pipes, valves, linings, and reactor casings. Additionally, PFA maintains its performance over a broad temperature range from -200°C to 260°C, demonstrating outstanding thermal stability.

Mechanical and Thermal Properties


PFA exhibits good mechanical strength and retains stability even at high temperatures. Key physical characteristics of PFA include:
  • Density: Approximately 2.12 - 2.17 g/cm³.
  • Temperature Range: Operates reliably from -200°C to 260°C and has a high melting point of around 305°C.
  • Corrosion Resistance: Withstands strong acids, bases, oxidizers, reducers, and most organic solvents, with only slight corrosion in fluorides and highly concentrated alkali solutions.
  • Insulation: Features very low dielectric loss and a resistivity of up to 10^18 ohm·cm, making it ideal for high-frequency applications.
  • Self-Lubrication: Possesses a low coefficient of friction, making it suitable for applications requiring low wear and no additional lubrication.
  • Non-Stick Surface: Its low surface energy prevents the adhesion of substances, ensuring easy cleaning and maintenance.
  • Weather Resistance: Excellent resistance to UV radiation and atmospheric aging, allowing it to remain stable in outdoor environments over time.

PFA Chemical resistance chart

How to use this chart

» Meaning of symbol: 
OK: Recommended. △: Must confirm if usable by testing in advanced. X: Not recommended.
» This chart only provides the result of a single chemical to material, if a client uses more than one kind of chemical at the same time, please choose material by experience.
» This chart is for reference only which is not applicable to all working environments. Please refer to design equipment according to practical experience.
Category Name PFA
Organic acids
Acetic acid OK (100%)
Acetic acid, glacial OK (< 121°C)
Acetic anhydride OK (< 93°C)
Citric acid OK (50% @ Room Temp)
△ (50% @ Boiling Point)
Organic compound Acetaldehyde OK (< 93°C)
Acetone OK (< 93°C)
Methyl alcohol OK (< 93°C)
Aniline N/A
Benzaldehyde OK (< 93°C)
Benzene OK (< 93°C)
Benzyl alcohol N/A
Benzyl chloride N/A
Corn oil OK (< 93°C)
Ethanol OK (< 93°C)
Ethylene glycol OK (< 149°C)
Fatty acid OK
Formaldehyde OK (< 93°C)
Formic acid OK (50% @ Room Temp)
△ (50% @ Boiling Point)
Hexane OK (< 93°C)
Lactic acid OK (10%)
Methanol OK (< 93°C)
Paraffin oil OK (< 93°C)
Petroleum OK (< 93°C)
Phenol N/A
Propane, liq OK (< 149°C)
Propanol OK (< 93°C)
Stearic acid OK
Tannic acid OK (< 93°C)
Tartaric acid OK (< 65°C)
Toluene OK (< 93°C)
Urea OK (< 177°C)
Inorganic compound Ammonia OK (< 149°C)
Ammonium chloride OK (< 93°C)
Ammonium hydroxide OK (< 93°C)
Ammonium nitrate OK (< 93°C)
Ammonium sulfate OK
Barium chloride OK (< 93°C)
Barium hydroxide OK (< 93°C)
Calcium chloride OK (< 93°C)
Calcium hydroxide OK (< 93°C)
Hydrochloric acid OK (< 10%)
Nitric acid OK (< 20%)
Phosphoric acid OK (< 50%)
Sodium carbonate OK (< 93°C)
Sodium hydroxide OK (< 40%)
Sulfuric acid OK (< 30%)
Sulfur dioxide OK (< 93°C)
Zinc chloride OK (< 93°C)
Zinc sulfate OK (< 93°C)

參考資料

  1. ^ Perolo-USA
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