author
Bobby Brown
Post 2016-09-09
UPE UHMWPE UHMW Material Characterization

Contents


What is UPE, UHMWPE, UHMW

Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene, (HMPE), or high-performance polyethylene (HPPE), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu. The longer chain serves to transfer load more effectively to the polymer backbone by strengthening intermolecular interactions. This results in a very tough material, with the highest impact strength of any thermoplastic presently made.

UHMWPE polymerization was commercialized by Ruhrchemie AG in the 1950s, a company that has undergone several name changes over the years. Today, UHMWPE powder materials, which can be directly molded into final product shapes, are produced by companies such as Ticona, Braskem, DSM, Teijin (Endumax), Celanese, and Mitsui. The processed UHMWPE is available in various forms, including fibers, sheets, and rods.

Chemical Properties and Applications

Structure and Chemical Resistance

Ultra-High Molecular Weight Polyethylene (UHMWPE) has a molecular structure similar to that of conventional polyethylene (PE), but its molecular weight is significantly higher, typically ranging 3.5 and 7.5 million amu (or Dalton). This unique structure imparts UHMWPE with exceptional mechanical strength and chemical resistance, particularly in the presence of acids, alkalis, and most organic solvents. Due to its ability to maintain stable performance in most environments, UHMWPE is widely used in both medical and industrial fields. Under laboratory conditions, it can withstand high concentrations of chemicals such as sulfuric acid, hydrochloric acid, and sodium hydroxide.

Mechanical Properties and Crystallinity

Mechanical Performance
Ultra-High Molecular Weight Polyethylene (UHMWPE) excels in mechanical performance, boasting wear resistance far superior to other thermoplastics. Its outstanding self-lubricating properties make it an ideal choice for industries that operate in high-wear environments, such as industrial machinery and transportation equipment. The exceptional durability of UHMWPE significantly extends the lifespan of components and reduces maintenance needs.
Crystallinity
While UHMWPE has a crystallinity similar to that of High-Density Polyethylene (HDPE), its ultra-high molecular weight grants it superior strength and toughness. This enhanced molecular structure results in material properties that are crucial for demanding applications, offering better performance under stress and increased resistance to deformation.

Melting Point and Thermal Expansion

Melting Point
Ultra-High Molecular Weight Polyethylene (UHMWPE) has a melting point around 130°C. Despite this relatively moderate melting point, the unique high molecular weight structure of UHMWPE provides remarkable thermal stability at elevated temperatures. This stability is essential for applications requiring consistent performance under thermal stress.
Thermal Expansion
UHMWPE exhibits a low coefficient of thermal expansion, which is advantageous in maintaining dimensional stability across temperature fluctuations. Unlike many other materials, UHMWPE does not become brittle at low temperatures. Even at temperatures below 0°C, UHMWPE retains its excellent toughness and strength, making it suitable for applications in cold environments.

Chemical resistance chart

How to use this chart
» Meaning of symbol:
OK: Recommended.
△: Must confirm if usable by testing in advanced.
X: Not recommended.
» This chart only provides the result of a single chemical to material, if a client uses more than one kind of chemical at the same time, please choose material by experience.
» This chart is for reference only which is not applicable to all working environments. Please refer to design equipment according to practical experience.
Category Name UPE
Organic acids Acetic acid OK (10% - 100% @ 20˚C)
△ (80% - 100% @ 60˚C)
Acetic acid, glacial N/A
Acetic anhydride N/A
Citric acid N/A
Organic compound
Acetaldehyde N/A
Acetone N/A
Methyl alcohol OK (20˚C, 60˚C)
Aniline N/A
Benzaldehyde N/A
Benzene △ (20˚C)X (60˚C)
Benzyl alcohol N/A
Benzyl chloride N/A
Corn oil N/A
Ethanol N/A
Ethylene glycol OK (20˚C, 60˚C)
Fatty acid N/A
Formaldehyde N/A
Formic acid OK (20˚C, 60˚C)
Hexane N/A
Lactic acid N/A
Methanol N/A
Paraffin oil N/A
Petroleum N/A
Phenol N/A
Propane, liq N/A
Propanol N/A
Stearic acid N/A
Tannic acid N/A
Tartaric acid N/A
Toluene X (20˚C, 60˚C)
Urea N/A
Inorganic compound
Ammonia OK (20˚C, 60˚C)
Ammonium chloride OK (20˚C, 60˚C)
Ammonium hydroxide N/A
Ammonium nitrate OK (20˚C, 60˚C)
Ammonium sulfate OK (20˚C, 60˚C)
Aqua regia N/A
Barium chloride N/A
Barium hydroxide N/A
Brine N/A
Calcium Chloride OK (20˚C, 60˚C)
Calcium hydroxide OK (20˚C, 60˚C)
Carbonic acid N/A
Chloric acid N/A
Chlorine N/A
Detergent N/A
Hydrobromic acid N/A
Hydrochloric acid OK (20˚C, 60˚C)
Hydrofluoric acid N/A
Hydrogen peroxide N/A
Nitric acid OK (0% - 30% @ 20˚C)
△ (30% - 50% @ 20˚C, 60˚C)
X (≥ 70% @ 20˚C, 60˚C)
X (Fuming @ 20˚C, 60˚C)
Phosphoric acid N/A
Potassium hydroxide OK (20˚C, 60˚C)
Potassium nitrate N/A
Potassium sulfate N/A
Sodium carbonate OK (20˚C, 60˚C)
Sodium hydroxide OK (20˚C, 60˚C)
Sodium nitrate N/A
Sulfuric acid OK (0% - 80% @ 20˚C)
△ (98% @ 20˚C)
X (80% - 98% @ 60˚C)
X (Fuming @ 20˚C, 60˚C)
Sulfur dioxide N/A

Reference

  1. ^ Ultra-high-molecular-weight polyethylene - wikipedia
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